- Product Name CHLOROMETHYL PHENYL SULFOXIDE
- cas 7205-94-9
- purity 99%
Others
CHLOROMETHYL PHENYL SULFOXIDE
High Quality Chinese Manufacturer supply 7205-94-9 CHLOROMETHYL PHENYL SULFOXIDE
- Molecular Formula: C7H7 Cl O S
- Molecular Weight: 174.651
- Vapor Pressure: 0.00125mmHg at 25°C
-
Melting Point:
33-35 °C
-
Boiling Point:
109-111 °C0.01 mm Hg
- Flash Point: 100 °C
- PSA： 36.28000
- Density: 1.35g/cm3
- LogP: 2.85620
CHLOROMETHYL PHENYL SULFOXIDE(Cas 7205-94-9) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 90, p. 4496, 1968 DOI: 10.1021/ja01018a078Synthesis, p. 831, 1986Tetrahedron Letters, 17, p. 613, 1976 |
|
General Description |
Chloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated. |
InChI:InChI=1/C7H7ClOS/c8-6-10(9)7-4-2-1-3-5-7/h1-5H,6H2
7205-94-9 Relevant articles
Aldehyde to Ketone Homologation Enabled by Improved Access to Thioalkyl Phosphonium Salts
Fragis, Meghan,Deobald, Jackson L.,Dharavath, Srinivas,Scott, Jeffrey,Magolan, Jakob
supporting information, p. 4548 - 4552 (2021/06/28)
Phosphines were previously unusable as P...
Selectivity switch in the aerobic oxygenation of sulfides photocatalysed by visible-light-responsive decavanadate
Li, Chifeng,Mizuno, Noritaka,Murata, Kei,Ishii, Kazuyuki,Suenobu, Tomoyoshi,Yamaguchi, Kazuya,Suzuki, Kosuke
supporting information, p. 3896 - 3905 (2020/07/09)
Nanometre-sized metal oxides are promisi...
Sulfone compound (by machine translation)
-
Paragraph 0046, (2017/10/06)
[Problem] to safely and conveniently, hi...
Chemoselective Oxidation of Sulfides to Sulfoxides with Urea-Hydrogen Peroxide Complex Catalysed by Diselenide
Bulman Page, Philip C.,Buckley, Benjamin R.,Elliott, Claire,Chan, Yohan,Dreyfus, Nicolas,Marken, Frank
supporting information, p. 80 - 82 (2015/12/26)
A highly selective catalytic oxidation s...
7205-94-9 Process route
-
-
7205-91-6
phenylthiomethyl chloride
-
-
7205-94-9
chloromethyl phenyl sulfoxide
Conditions
| Conditions | Yield |
|---|---|
|
With
n-C4F9; perfluoro-cis-2,3-dialkyloxaziridine; n-C3F7;
In
chloroform; trichlorofluoromethane;
at -40 ℃;
for 0.5h;
|
95%
|
|
With
aluminum oxide; sodium chlorite;
manganese(III) acetylacetonate;
In
acetone;
at 20 ℃;
for 0.5h;
|
95%
|
|
With
aluminum oxide; calcium hypochlorite;
In
dichloromethane;
at 30 ℃;
for 0.833333h;
|
91%
|
|
With
5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride; dihydrogen peroxide;
In
ethanol;
at 20 ℃;
for 0.0666667h;
|
90%
|
|
With
1-butyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate;
In
acetonitrile;
for 1.08333h;
Heating;
|
89%
|
|
With
nitric acid; phosphorus pentoxide; silica gel;
In
water;
for 0.0833333h;
|
88%
|
|
With
nitric acid; phosphorus pentoxide; silica gel;
for 0.0833333h;
|
88%
|
|
With
nitrourea; silica-gel-supported sulfuric acid; ammonium bromide;
In
dichloromethane;
at 20 ℃;
for 2.66667h;
|
84%
|
|
With
dihydrogen peroxide;
vanadium(III) chloride;
In
tetrahydrofuran;
at 20 ℃;
for 0.583333h;
|
83%
|
|
With
sulfuryl dichloride; water; silica gel;
In
dichloromethane;
for 2h;
Ambient temperature;
|
80.8%
|
|
With
iron(III) chloride; periodic acid;
In
acetonitrile;
at 20 ℃;
for 0.0833333h;
|
80%
|
|
With
N-Bromosuccinimide;
In
methanol; water;
at 0 - 5 ℃;
|
42%
|
|
With
dihydrogen peroxide; zinc dibromide;
In
1,4-dioxane; water;
at 20 ℃;
for 6h;
Air atmosphere;
|
60 %Chromat.
|
|
With
diphenyl diselenide; urea hydrogen peroxide adduct;
In
dichloromethane;
at 20 ℃;
for 24h;
|
96 %Spectr.
|
-
-
100-68-5
methyl-phenyl-thioether
-
-
7205-94-9
chloromethyl phenyl sulfoxide
Conditions
| Conditions | Yield |
|---|---|
|
With
sulfuryl dichloride; silver nitrate;
In
acetonitrile;
at 0 - 25 ℃;
for 1h;
|
84%
|
|
methyl-phenyl-thioether;
With
sulfuryl dichloride;
In
dichloromethane;
for 2h;
Heating;
With
sulfuryl dichloride; water; silica gel;
In
dichloromethane;
at 20 ℃;
for 2h;
|
84%
|
|
Multi-step reaction
with
2
steps
1: N-chloro-succinimide / chlorobenzene / 3 h / 35 °C / Inert atmosphere
2: N-Bromosuccinimide / water; methanol / 0 - 5 °C
With
N-chloro-succinimide; N-Bromosuccinimide;
In
methanol; water; chlorobenzene;
|
|
|
Multi-step reaction
with
2
steps
1: dihydrogen peroxide / water; methanol / 24 h / 0 - 20 °C
2: N-chloro-succinimide / dichloromethane / 48 h / 20 °C
With
N-chloro-succinimide; dihydrogen peroxide;
In
methanol; dichloromethane; water;
|
7205-94-9 Upstream products
-
186581-53-3
diazomethane
-
4972-29-6
benzenesulphinyl chloride
-
60-29-7
diethyl ether
-
7205-91-6
phenylthiomethyl chloride
7205-94-9 Downstream products
-
7205-98-3
chloromethyl phenyl sulfone
-
21849-29-6
2-chloro-1,1-diphenyl-2-(phenylsulfinyl)ethanol
-
70872-74-1
(1-chloro-octane-1-sulfinyl)-benzene
-
70872-73-0
(1-chloro-decane-1-sulfinyl)-benzene
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