- Product Name 2-METHYL-1-UNDECENE
- cas 18516-37-5
- purity 99%
Pharmaceutical
Cost-effective and customizable 2-METHYL-1-UNDECENE 18516-37-5 supplier
- Molecular Formula: C12H24
- Molecular Weight: 168.323
- Vapor Pressure: 0.00366mmHg at 25°C
- Melting Point: -40.77°C
- Refractive Index: n20/D 1.432(lit.)
- Boiling Point: 209.5°Cat760mmHg
- Flash Point: 72.2°C
- PSA： 0.00000
- Density: 0.759g/cm3
- LogP: 4.70320
2-METHYL-1-UNDECENE(Cas 18516-37-5) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 94, p. 4758, 1972 DOI: 10.1021/ja00768a069Tetrahedron Letters, 19, p. 2807, 1978 |
InChI:InChI=1/C9H12N2O.ClH/c1-2-12-8-6-4-3-5-7(8)9(10)11;/h3-6H,2H2,1H3,(H3,10,11);1H
18516-37-5 Relevant articles
-
Shono,T. et al.
, p. 2807 - 2810 (1978)
-
Synthesis of α-Tertiary Amine Derivatives by Intermolecular Hydroamination of Unfunctionalized Alkenes with Sulfamates under Trifluoromethanesulfonic Acid Catalysis
Fei, Jun,Wang, Zhen,Cai, Zheren,Sun, Hao,Cheng, Xu
supporting information, p. 4063 - 4068 (2016/01/25)
An efficient and mild trifluoromethanesu...
Simple, chemoselective, catalytic olefin isomerization
Crossley, Steven W. M.,Barabé, Francis,Shenvi, Ryan A.
supporting information, p. 16788 - 16791 (2015/01/09)
Catalytic amounts of Co(SaltBu,tBu)Cl an...
Cylindrocyclophane biosynthesis involves functionalization of an unactivated carbon center
Nakamura, Hitomi,Hamer, Hilary A.,Sirasani, Gopal,Balskus, Emily P.
supporting information, p. 18518 - 18521 (2013/01/15)
The cylindrocyclophanes are a family of ...
Iron thiolate complexes: Efficient catalysts for coupling alkenyl halides with alkyl grignard reagents
Cahiez, Gerard,Gager, Olivier,Buendia, Julien,Patinote, Cindy
supporting information; experimental part, p. 5860 - 5863 (2012/07/01)
Ironing out the kinks: Efficient new cat...
18516-37-5 Process route
-
-
87057-46-3
2-Methyl-2-nonyl-thiirane
-
-
7045-71-8
2-methylundecane
-
-
18516-37-5
2-methyl-undec-1-ene
Conditions
| Conditions | Yield |
|---|---|
|
With
nickel;
In
ethanol;
at 90 ℃;
for 0.5h;
Yield given. Yields of byproduct given;
|
|
|
With
nickel;
In
ethanol;
at 90 ℃;
for 0.5h;
Product distribution;
various temperature and various reagents (Li/EtNH2, Zn/CH3COOH, tributyltin hydride);
|
-
-
1309476-82-1
1,1-dibromo-2-methylundec-1-ene
-
-
18516-37-5
2-methyl-undec-1-ene
-
-
629-49-2
2-decyne
-
-
141941-53-9
(+/-)-3-hexyl-1-methylcyclopentene
Conditions
| Conditions | Yield |
|---|---|
|
With
lanthanum; iodine;
In
tetrahydrofuran;
at 67 ℃;
for 3h;
Inert atmosphere;
|
59 %Chromat.
15 %Chromat. 8 %Chromat. |
18516-37-5 Upstream products
-
17049-49-9
octylmagnesium bromide
-
563-47-3
3-Chloro-2-methylpropene
-
112-12-9
methyl nonyl ketone
-
68659-61-0
methyltriphenylphosphorane
18516-37-5 Downstream products
-
10522-26-6
2-methyl-1-undecanol
-
61868-05-1
2,4-dimethyltridecane
-
112-12-9
methyl nonyl ketone
-
1408005-86-6
(E)-1,3-dimethoxy-5-(2-methylundec-1-en-1-yl)benzene
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